A Simple Synthetic Route to [Rh(acac)(CO)(NHC)] Complexes: Ligand Property Diagnostic Tools and Precatalysts
نویسندگان
چکیده
An operationally simple, user and eco-friendly synthetic protocol for the synthesis of [Rh(acac)(CO)(NHC)] complexes is described. Insights into mechanism are provided using operando spectroscopy. The spectroscopic fingerprints these correlated to NHCs reported electron-donating descriptor values, highlighting a new strategy evaluate carbenes’ electronic properties. assessment in catalytic applications also reported, showing promising results hydrogenation aromatic ketones.
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ژورنال
عنوان ژورنال: European Journal of Inorganic Chemistry
سال: 2021
ISSN: ['1434-1948', '1099-0682']
DOI: https://doi.org/10.1002/ejic.202100479